Pseudo-first-order rate constant calculator
Many bimolecular reactions are studied under pseudo-first-order conditions so that the observed decay of the limiting reactant looks first-order while the true elementary step remains second-order.
Run — free
Runs in your browser. Free, unlimited — your data never leaves this page.
The shortcut is simple but easy to mis-handle by hand: multiply the second-order rate constant k by the nearly constant excess concentration to obtain the observed constant k prime. This capability does that multiplication deterministically, rejects negative concentrations with a clear invalid input error, and returns structured JSON that lab notebooks, kinetics tutorials, and automated homework checkers can pin in tests. Students preparing SN2 or enzyme-kinetics demos, process chemists sizing continuous stirred tanks, and data pipelines that normalize literature k2 values into observed first-order constants all get the same contract whether they use the free in-browser tool or the prepaid API at $0.002 per successful item.
How to use it
Enter your values in the form above. The tool checks them before calculating and shows the result on the same page.
Check your inputs
Use the labels and units shown next to each field. If something is missing or outside the allowed range, the page points to the field to fix.
Use it again or automate it
Use the browser tool for individual checks and the API when you need the same capability in an automated workflow.
What you can do with it
Get an answer now
Enter one set of values and see the result without building a spreadsheet or script.
Compare scenarios
Change one value at a time and rerun the calculation to understand what affects the result.
Automate repeated work
Use the API when the same calculation needs to run inside your product or workflow.
FAQ
How do I use this capability?
Complete the fields above and run it on this page. The form highlights anything that needs attention.
For developers — API access
Everything on this page is available programmatically. This section is for teams who want to wire it into their own systems; everyone else can just use the tool above.
API endpoint
Prefer to automate it? One authenticated POST creates the task; the result comes back by webhook or a signed link. The same capability also runs here on the web, by email and from Telegram — and soon from our app too.
Call it from your stack
curl -X POST https://api.kit.forhosting.com/chem/pseudo-first-order \
-H "Authorization: Bearer $KIT_KEY" \
-H "Content-Type: application/json" \
-d '{"k":0.05,"concentration":0.5}'const res = await fetch("https://api.kit.forhosting.com/chem/pseudo-first-order", {
method: "POST",
headers: {
"Authorization": `Bearer ${process.env.KIT_KEY}`,
"Content-Type": "application/json"
},
body: JSON.stringify({
"k": 0.05,
"concentration": 0.5
})
});
const { task_id } = await res.json();import os, requests
res = requests.post(
"https://api.kit.forhosting.com/chem/pseudo-first-order",
headers={"Authorization": f"Bearer {os.environ['KIT_KEY']}"},
json={
"k": 0.05,
"concentration": 0.5
},
)
task_id = res.json()["task_id"]<?php
$res = file_get_contents("https://api.kit.forhosting.com/chem/pseudo-first-order", false, stream_context_create([
"http" => [
"method" => "POST",
"header" => "Authorization: Bearer " . getenv("KIT_KEY") . "\r\nContent-Type: application/json",
"content" => '{"k":0.05,"concentration":0.5}',
],
]));
$task = json_decode($res, true);body := bytes.NewBufferString(`{"k":0.05,"concentration":0.5}`)
req, _ := http.NewRequest("POST", "https://api.kit.forhosting.com/chem/pseudo-first-order", body)
req.Header.Set("Authorization", "Bearer "+os.Getenv("KIT_KEY"))
req.Header.Set("Content-Type", "application/json")
res, _ := http.DefaultClient.Do(req)Example request
{
"k": 0.05,
"concentration": 0.5
}Example response
{
"task_id": "tsk_a1b2c3d4e5f6a1b2c3d4e5f6",
"type": "chem.pseudo_first_order",
"status": "queued",
"_links": {
"result": "/tasks/tsk_…/result"
}
}The API is asynchronous: the call returns a task_id immediately and the result arrives by webhook. Polling is capped at 1 req/s per task.
Pricing
Published price — no tokens, no invented credits. A failed task is never charged.
Errors
| HTTP | Code | Meaning |
|---|---|---|
401 | unauthorized | Missing or invalid API key. |
402 | insufficient_balance | Your balance doesn't cover the task price. |
404 | unknown_type | That task type doesn't exist. |
429 | rate_limited | Too many requests. Use the webhook instead of polling. |